Uses of Ammonium Bicarbonate in Baking

Ammonium Bicarbonate (NH₄HCO₃) is a baking ingredient used for its leavening effect. This compound can be dated back to medieval Europe; the people of those eras were already employing ammonium bicarbonate in food preparation to enhance the fluffiness of the food and the texture of cookies and bread.
Ammonium bicarbonate was originally derived from hartshorn salt, a product obtained from animal horns or bones. With the advancement of chemical science, people have been able to synthesize ammonium bicarbonate powder artificially. For this reason, ammonium bicarbonate has become a cheaper leavening agent used in the baking sector.
Ammonium bicarbonate in food is decomposed to carbon dioxide (CO₂), ammonia motor, and water vapor (NH₃, H₂O) when exposed to high temperatures that are usually present in the process of cooking food. These released gases help make the dough puff up, the kind of result that is expected. It differs from the commonly known sodium bicarbonate (baking soda) and baking powder while ammonium bicarbonate E503 is fully decomposable with no formation of alkaline residues. It is more suitable in bread making for products that need light and crispy texture products such as ammonium bicarbonate in cookies, thin crisp biscuits, and waffles.
However, with the emergence of other baking powder and chemical leavening agents, in the current modern baking industry, ammonium bicarbonate is still indispensable in certain fields of baking, especially in industrial baked products of low moisture and high bake temperature. Thus, ammonium bicarbonate in baking is highly significant.
How to Use Ammonium Bicarbonate in Baking?
Complete Volatility
Thus, the most salient feature of ammonium bicarbonate in baking is its complete volatility. Baking is the process where it decomposes into ammonia (NH3), carbon dioxide (CO2), and water (H2O).
NH₄HCO₃ → NH₃ + CO₂ + H₂O
These three products are either gases themselves, or evaporable liquids that sublime at baking temperatures, and therefore do not deposit anything behind. This is different from Ammonium Bicarbonate vs Baking Soda in that it leads to the formation of sodium salt. This property makes ammonium bicarbonate in food most appropriate for foods that are less moist and possess a crispy texture after baking.
Ammonium bicarbonate E503 creates 40 percent more gas than baking soda, thus less of it can be used to get the same expanding Agent. In particular, this changes the nature of the developed gas and how it is distributed in the dough to be finer and finely dispersed in pore size; ideal for baked goods that seek higher texturization.
Neutral pH Value
Different from other chemical leavening agents, ammonium bicarbonate in food does not affect dough’s pH value after decomposition and this is a special requirement for certain formulas. For instance, in ammonium bicarbonate in cookies, a neutral pH prevents colors from fading or changing through discoloration as a result of changes in pH levels.
Texture Shaping Ability
Ammonium bicarbonate powder itself generates gas when baking and thus forms special physical structures, namely, fine and uniform pores and crisp texture. It gives it several advantages for the creation of hard biscuits, thin cookies, and definite types of conventional pastries. For other leavening agents, it has almost been hard for them to offer the “crispy but not hard” mouthfeel that it produces.
Process Adaptability
In the contemporary food industry, ammonium bicarbonate in food is well-compatible with different processes of baking. They can be used individually and in conjunction with other leavening agents such as yeast or Baking Soda which would enhance the production of various products. Especially when industrialization is being used at a large scale, it ensures product quality through process stability and controllability.
Uses of Ammonium Bicarbonate in Different Baking
Frequently, ammonium bicarbonate uses occur as a baking ingredient that greatly aids various baked food products. Due to its fast production of carbon dioxide gas and total acid-leavable nature, the substance has versatile usage in baked foods when aiming for crispiness, lighter texture, or layering.
Crispy Cookies (such as cookies and thin crispy biscuits)
Ammonium bicarbonate in cookies also facilitates an expulsion of carbon dioxide which contributes to making the cookies fluffy and have a porous structure that enables it to have the desired texture of melting in the mouth or the crispiness. Usage: Normally, 0.5%-2% of the flour weight; attention should be paid to avoid the smell of remaining ammonia due to over-use.
Flaky Pastries (such as egg tart crusts and puff pastries)
Ammonium bicarbonate E503 works with butter layers; as the gas expands rapidly, the layered pastry turns out to be “thousand-layer crispy”. It is safe from residues of some leavening agents that may be left behind as it has none, which makes it have a pure taste.
Thin Sheet Snacks (such as rice cakes and prawn crackers)
The large amount of gas produced by ammonium bicarbonate powder instant decomposition at high temperatures causes thin sheet snacks to expand rapidly and form a light and crispy structure. It enhances the crispness of products while reducing moisture content, extending shelf life.
Traditional Pastries (such as Chinese walnut cookies and almond cookies)
Uses of ammonium bicarbonate control the dough’s extensibility and inhibit the shrinking of the dough during the shaping period. It encourages the Maillard reaction, thus providing traditional pastries with a fragrance and a copper hue.

Comparison Between Ammonium Bicarbonate and Other Leavening Agents
Advantages of Ammonium Bicarbonate
- Ammonium bicarbonate uses to provide a very good leavening agent when used in small quantities hence can be used effectively in the industrial process.
- Among them, its dissolving character is most suitable for Application in Low-Moisture Products like Biscuits – Cookies, Extremely Thin Biscuits, and layered Pastries.
- It is known that ammonium bicarbonate E503 does not contain any sodium ions and can be used effectively for Sodium-Free leavening for special dietary needs.
Limitations of Ammonium Bicarbonate Usage
- When the temperature of baking is low, or the amount used is large, the smell of leavening ammonium bicarbonate will exist.
- It is not suitable for thick and moist baked products like traditional cake and yeast bread since fast expansion will cause product breakdown.
Alternatives with Other Leavening Agents
Combined Use with Baking Soda (NaHCO₃)
- Baking soda decomposes slower hence it will act as a supporting agent to the fast-producing gas that is ammonium bicarbonate E503.
- Baking soda can adjust the pH level where the level of acidity in the food is high by using acidic such as citric acid or lactic acid.
Modern Alternatives
- Aluminum-free baking powder is another form that is safer to use but it does not offer the ammonium bicarbonate uses in creating crispness in baked products.
- Yeast or natural starters are excellent for dense bread but can’t be used to replace ammonium bicarbonate in baking, which is very efficient in baking.
Conclusion
The uses of ammonium bicarbonate baking are highly significant. Ammonium bicarbonate is still in use in baking, especially in industrial-scale baking, where there is a need for crispy products and efficient leavening. Nevertheless, ammonium bicarbonate in baking today is still used as an ideal baking powder in low-moisture products to produce quality crispy, and sodium-free baked goods. For more details on this, please contact the Mondstar team.
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